using DevExpress.XtraGrid.Columns;
GridColumn columnDiff = new GridColumn();
columnDiff.FieldName = "amountDiff";
columnDiff.Caption = "Diff";
columnDiff.UnboundType = DevExpress.Data.UnboundColumnType.Decimal;
columnDiff.UnboundExpression = "[TransactionAmount] - [AmountDroppped]";
gridView1.Columns.Add(columnDiff);
To conditionally highlight some specific rows I suggest you use the Style Format Conditions feature:
using DevExpress.XtraGrid;
StyleFormatCondition condition = new DevExpress.XtraGrid.StyleFormatCondition();
condition.Appearance.BackColor = Color.Red;
condition.Appearance.Options.UseBackColor = true;
condition.ApplyToRow = true;
condition.Condition = FormatConditionEnum.Expression;
condition.Expression = "([TransactionAmount] - [AmountDroppped]) > 400";
gridView1.FormatConditions.Add(condition);