it seems you have one record with all the options and it will bind in to a one item in radio button list. what you can do is; get the record and create list with all the options and bind it to radio button list as below
var item= (from a in TraningExamQuestionBank
where a.TrainingExamQuestionBankId == QuestionId
select new
{
a.OptionA,
a.OptionB,
a.OptionC,
a.OptionD,
a.OptionE,
}).FirstOrDefault();
if(item !=null)
{
List<string> items = new List<string>(){ item.OptionA, item.OptionB, item.OptionC, item.OptionD, item.OptionE};
RadioButtonList1.DataSource = items;
RadioButtonList1 DataBind();
}