All you have to do is to debug your code.
Take a look at your code - a reason seems to be quite obvious (see my comments):
foreach(HtmlAgilityPack.HtmlNode item in nodes)
{
s[0] = item.InnerText;
ss = (string[])s.ToArray();
dataGridView2.Rows.Add(ss[0]);
dataGridView2.Rows.Add(ss[0]);
}