The only issue i see with your code is you have the array declaration wrong in your MinVal method.
The following code, only thing corrected being the array, compiles and runs as expected.
static void Main(string[] args)
{
Min obj1 = new Min();
obj1.MinVal(1, 2, 3, 4, 5);
Console.ReadLine();
}
class Min
{
public void MinVal(params int[] numbers)
{
for (int i = 0; i < numbers.Length; i++)
{
Console.WriteLine(numbers[i]);
Console.WriteLine();
}
}
}