Do it like this :-
on click event do the following coding;-
private void button1_Click(object sender, EventArgs e)
{
string phase = textBox1.Text;
char[] delim = new char[] {'@'};
string[] word;
word = phase.Split(delim, 2);
listBox1.Items.Add(word[0]);
textbox1.clear();
textbox1.focus();
}