Without knowing what database your are using I can't give you exact syntax, but this is a basic SQL statement that would pull a list of services that do not have a customer:
SELECT * FROM tblService LEFT OUTER JOIN tblCustomer ON tblService.CustomerID = tblCustomer.CustomerID WHERE tblService.CustomerID IS NULL
If you want more help, you'll have to provide more information about your project and which part you are stuck. Click the Improve question link to add that. It's also helpful if you post the relevant code you are having trouble with.