Well, if EF6 is configured approrpiately, it should create your schema on the app's first usage. An Alternative is to "generate scripts" in your database inside SSMS, and simply run those scripts to create the schema inside the database, and even populate static data in the appropriate tables.
I wrote a 6-part article series that describes a method for running agents in SQL Express, which provides an example of generating the schema from SQL scripts from within an application.
SQLXAgent - Jobs for SQL Express - Part 1 of 6[
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