Hi
I think the
System.Xml.XPath
namespace coming under
System.Xml.dll
This dll you can find in the folder
C:\Program Files\Reference Assemblies\Microsoft\Framework\.NETFramework\v3.5\Profile\Client
C:\Program Files\Reference Assemblies\Microsoft\Framework\.NETFramework\v4.0\Profile\Client
Or you can just use
Visual Studio Project -> Right Click -> AddReference -> .NET -> System.Xml.dll to find dll.
Can you please check in the below mentioned folder also.
C:\Program Files\Microsoft SDKs\Silverlight\v4.0\Libraries\Client
There you can find a dll named
System.Xml.XPath.dll
Regards
Dominic